CobaltMaghrebV1, Main, Exploration, bibRecord, 000169

Bis(2,6-dimethylanilinium) diaquabis(dihydrogen diphosphato-κ2O,O′)cobaltate(II)

Identifieur interne : 000169 ( Main/Exploration ); précédent : 000168; suivant : 000170

Bis(2,6-dimethylanilinium) diaquabis(dihydrogen diphosphato-κ2O,O′)cobaltate(II)

Auteurs : Ahlem Ben Saad [Tunisie] ; Ahmed Selmi [Tunisie] ; Mohamed Rzaigui [Tunisie] ; Samah Toumi Akriche [Tunisie]

Source :

Acta Crystallographica Section E: Structure Reports Online [ 1600-5368 ] ; 2014.

RBID : PMC:3998415

Abstract

In the title compound, (C₈H₁₂N)₂[Co(H₂P₂O₇)₂(H₂O)₂], the Co²⁺ ion lies on a crystallographic inversion centre and adopts a slightly distorted octahedral CoO₆ coordination geometry arising from two chelating diphosphate [H₂P₂O₇]²⁻ ligands and two trans water molecules. In the crystal, the components are linked by O—H⋯O, N—H⋯O and C—H⋯O hydrogen bonds and weak aromatic π–π stacking [shortest centroid–centroid separation = 3.778 (2) Å] interactions. (001) layers of alternating organic cations and complex inorganic anions are apparent.

Url:

http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998415

DOI: 10.1107/S1600536814002530
PubMed: 24764950
PubMed Central: 3998415

Affiliations:

Tunisie

Le document en format XML

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<front><div type="abstract" xml:lang="en"><p>In the title compound, (C<sub>8</sub>
H<sub>12</sub>
N)<sub>2</sub>
[Co(H<sub>2</sub>
P<sub>2</sub>
O<sub>7</sub>
)<sub>2</sub>
(H<sub>2</sub>
O)<sub>2</sub>
], the Co<sup>2+</sup>
 ion lies on a crystallographic inversion centre and adopts a slightly distorted octahedral CoO<sub>6</sub>
 coordination geometry arising from two chelating diphosphate [H<sub>2</sub>
P<sub>2</sub>
O<sub>7</sub>
]<sup>2−</sup>
 ligands and two <italic>trans</italic>
 water molecules. In the crystal, the components are linked by O—H⋯O, N—H⋯O and C—H⋯O hydrogen bonds and weak aromatic π–π stacking [shortest centroid–centroid separation = 3.778 (2) Å] interactions. (001) layers of alternating organic cations and complex inorganic anions are apparent.</p>
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Serveur d'exploration sur le cobalt au Maghreb

Bis(2,6-dimethylanilinium) diaquabis(dihydrogen diphosphato-κ2O,O′)cobaltate(II)

Bis(2,6-dimethylanilinium) diaquabis(dihydrogen diphosphato-κ2O,O′)cobaltate(II)

Source :

Abstract

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	Serveur d'exploration sur le cobalt au Maghreb
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Serveur d'exploration sur le cobalt au Maghreb

Bis(2,6-di­methyl­anilinium) di­aqua­bis­(di­hydrogen diphosphato-κ2O,O′)cobaltate(II)

Bis(2,6-di­methyl­anilinium) di­aqua­bis­(di­hydrogen diphosphato-κ2O,O′)cobaltate(II)

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Abstract

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Bis(2,6-dimethylanilinium) diaquabis(dihydrogen diphosphato-κ2O,O′)cobaltate(II)

Bis(2,6-dimethylanilinium) diaquabis(dihydrogen diphosphato-κ2O,O′)cobaltate(II)